“Using the organic materials as a platform, we created highly functional micro- and nanoparticles that can attach to metals like neodymium and separate them from the fluid that surrounds them,” Sheikhi said. “Via electrostatic interactions, the negatively-charged micro- and nano-scale materials bind to positively-charged neodymium ions, separating them.”
To prepare the experiment, Sheikhi’s team ground up tomato peel and corncob and cut wood pulp and cotton paper into small, thin pieces and soaked them in water. Then, they chemically reacted these materials in a controlled fashion to disintegrate them into three distinct fractions of functional materials: microproducts, nanoparticles and solubilized biopolymers. Adding the microproducts or nanoparticles to neodymium solutions triggered the separation process, resulting in the capture of neodymium samples.
In this most recent paper, Sheikhi improved upon the separation process demonstrated in previous work and extracted larger sample sizes of neodymium from less concentrated solutions.
Sheikhi plans to extend his separation mechanism into real-world scenarios and partner with interested industries to further test the process.
“In the near future, we want to test our process on realistic industrial samples,” Sheikhi said.
“We also hope to tune the selectivity of the materials toward other rare earth elements and precious metals, like gold and silver, to be able to separate those from waste products as well.”
In addition to Sheikhi, Mica Pitcher, Penn State doctoral student in chemistry and first author on the paper; Breanna Huntington, Penn State undergraduate student in agricultural and biological engineering; and Juliana Dominick, Penn State undergraduate student in biomedical engineering, contributed to the paper.
Penn State supported this work.