PI Global Investments
Precious Metals

Anodic Pd membrane H2 extraction enhances thermochemical dehydrogenation


  • Sattler, J. J. H. B., Ruiz-Martinez, J., Santillan-Jimenez, E. & Weckhuysen, B. M. Catalytic dehydrogenation of light alkanes on metals and metal oxides. Chem. Rev. 114, 10613–10653 (2014).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Gunanathan, C. & Milstein, D. Applications of acceptorless dehydrogenation and related transformations in chemical synthesis. Science 341, 1229712 (2013).

    Article 
    ADS 
    PubMed 

    Google Scholar
     

  • Chen, L. et al. Reversible dehydrogenation and rehydrogenation of cyclohexane and methylcyclohexane by single-site platinum catalyst. Nat. Commun. 13, 1092 (2022).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Sheintuch, M. & Simakov, D. S. A. Alkanes dehydrogenation. In Membrane Reactors for Hydrogen Production Processes (eds De Falco, M. et al.) 183–200 https://doi.org/10.1007/978-0-85729-151-6_9 (Springer, 2011).

  • Shu, J., Grandjean, B. P. A., Van Neste, A. & Kaliaguine, S. Catalytic palladium-based membrane reactors: a review. Can. J. Chem. Eng. 69, 1036–1060 (1991).

    Article 
    CAS 

    Google Scholar
     

  • Malerød-Fjeld, H. et al. Thermo-electrochemical production of compressed hydrogen from methane with near-zero energy loss. Nat. Energy 2, 923–931 (2017).

    Article 
    ADS 

    Google Scholar
     

  • Lin, Y. S. Inorganic membranes for process intensification: challenges and perspective. Ind. Eng. Chem. Res. 58, 5787–5796 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Habib, M. A. et al. Palladium-alloy membrane reactors for fuel reforming and hydrogen production: a review. Energy Fuels 35, 5558–5593 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Kurimoto, A., Sherbo, R. S., Cao, Y., Loo, N. W. X. & Berlinguette, C. P. Electrolytic deuteration of unsaturated bonds without using D2. Nat. Catal. 3, 719–726 (2020).

    Article 
    CAS 

    Google Scholar
     

  • Han, G., Li, G. & Sun, Y. Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%. Nat. Catal. 6, 224–233 (2023).

    Article 
    CAS 

    Google Scholar
     

  • IUPAC-NIST Solubility Data Series Database Version 1.0 https://doi.org/10.18434/T4QC79 (NIST, 2007).

  • Basile, A. Hydrogen production using Pd-based membrane reactors for fuel cells. Top. Catal. 51, 107–122 (2008).

    Article 
    CAS 

    Google Scholar
     

  • Mukherjee, S., Devaguptapu, S. V., Sviripa, A., Lund, C. R. F. & Wu, G. Low-temperature ammonia decomposition catalysts for hydrogen generation. Appl. Catal. B Environ. 226, 162–181 (2018).

    Article 
    CAS 

    Google Scholar
     

  • Hill, A. K. & Torrente-Murciano, L. In-situ H2 production via low temperature decomposition of ammonia: insights into the role of cesium as a promoter. Int. J. Hydrogen Energy 39, 7646–7654 (2014).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Hill, A. K. & Torrente-Murciano, L. Low temperature H2 production from ammonia using ruthenium-based catalysts: synergetic effect of promoter and support. Appl. Catal. B Environ. 172–173, 129–135 (2015).

    Article 

    Google Scholar
     

  • Furusawa, T., Kuribara, H., Kimura, K., Sato, T. & Itoh, N. Development of a Cs-Ru/CeO2 spherical catalyst prepared by impregnation and washing processes for low-temperature decomposition of NH3: characterization and kinetic analysis results. Ind. Eng. Chem. Res. 59, 18460–18470 (2020).

    Article 
    CAS 

    Google Scholar
     

  • Wang, Z., Qu, Y., Shen, X. & Cai, Z. Ruthenium catalyst supported on Ba modified ZrO2 for ammonia decomposition to COx-free hydrogen. Int. J. Hydrogen Energy 44, 7300–7307 (2019).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Hu, Z., Mahin, J., Datta, S., Bell, T. E. & Torrente-Murciano, L. Ru-based catalysts for H2 production from ammonia: effect of 1D support. Top. Catal. 62, 1169–1177 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Ju, X. et al. Mesoporous Ru/MgO prepared by a deposition-precipitation method as highly active catalyst for producing COx-free hydrogen from ammonia decomposition. Appl. Catal. B Environ. 211, 167–175 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Fang, H. et al. Dispersed surface Ru ensembles on MgO(111) for catalytic ammonia decomposition. Nat. Commun. 14, 647 (2023).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Yu, P. et al. Effects of alkaline earth metal amides on Ru in catalytic ammonia decomposition. J. Phys. Chem. C 120, 2822–2828 (2016).

    Article 
    CAS 

    Google Scholar
     

  • Kishida, K. et al. Large oblate hemispheroidal ruthenium particles supported on calcium amide as efficient catalysts for ammonia decomposition. Chem. Eur. J. 24, 7976–7984 (2018).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Lim, D.-K. et al. Solid acid electrochemical cell for the production of hydrogen from ammonia. Joule 4, 2338–2347 (2020).

    Article 
    CAS 

    Google Scholar
     

  • García-García, F. R., Ma, Y. H., Rodríguez-Ramos, I. & Guerrero-Ruiz, A. High purity hydrogen production by low temperature catalytic ammonia decomposition in a multifunctional membrane reactor. Catal. Commun. 9, 482–486 (2008).

    Article 

    Google Scholar
     

  • Itoh, N., Kikuchi, Y., Furusawa, T. & Sato, T. Tube-wall catalytic membrane reactor for hydrogen production by low-temperature ammonia decomposition. Int. J. Hydrogen Energy 46, 20257–20265 (2021).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Itoh, N., Oshima, A., Suga, E. & Sato, T. Kinetic enhancement of ammonia decomposition as a chemical hydrogen carrier in palladium membrane reactor. Catal. Today 236, 70–76 (2014).

    Article 
    CAS 

    Google Scholar
     

  • Li, G. et al. Preparation of a novel bimodal catalytic membrane reactor and its application to ammonia decomposition for COx-free hydrogen production. Int. J. Hydrogen Energy 37, 12105–12113 (2012).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Nagatake, S. et al. Dehydrogenation of methylcyclohexane over Pt/TiO2 catalyst. Catal. Lett. 146, 54–60 (2016).

    Article 
    CAS 

    Google Scholar
     

  • Kim, S. et al. Zeolite membrane-based low-temperature dehydrogenation of a liquid organic hydrogen carrier: a key step in the development of a hydrogen economy. Adv. Sci. 11, 2403128 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Gora, A., Pacheco Tanaka, D. A., Mizukami, F. & Suzuki, T. M. Lower temperature dehydrogenation of methylcyclohexane by membrane-assisted equilibrium shift. Chem. Lett. 35, 1372–1373 (2006).

    Article 
    CAS 

    Google Scholar
     

  • Ferreira-Aparicio, P., Rodriguez-Ramos, I. & Guerrero-Ruiz, A. On the performance of porous Vycor membranes for conversion enhancement in the dehydrogenation of methylcyclohexane to toluene. J. Catal. 212, 182–192 (2002).

    Article 
    CAS 

    Google Scholar
     

  • Oda, K. et al. Dehydrogenation of methylcyclohexane to produce high-purity hydrogen using membrane reactors with amorphous silica membranes. Ind. Eng. Chem. Res. 49, 11287–11293 (2010).

    Article 
    CAS 

    Google Scholar
     

  • Li, G., Niimi, T., Kanezashi, M., Yoshioka, T. & Tsuru, T. Equilibrium shift of methylcyclohexane dehydrogenation in a thermally stable organosilica membrane reactor for high-purity hydrogen production. Int. J. Hydrogen Energy 38, 15302–15306 (2013).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Niimi, T. et al. Preparation of BTESE-derived organosilica membranes for catalytic membrane reactors of methylcyclohexane dehydrogenation. J. Membr. Sci. 455, 375–383 (2014).

    Article 
    CAS 

    Google Scholar
     

  • Meng, L. et al. Methylcyclohexane dehydrogenation for hydrogen production via a bimodal catalytic membrane reactor. AIChE J. 61, 1628–1638 (2015).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Li, G., Yada, K., Kanezashi, M., Yoshioka, T. & Tsuru, T. Methylcyclohexane dehydrogenation in catalytic membrane reactors for efficient hydrogen production. Ind. Eng. Chem. Res. 52, 13325–13332 (2013).

    Article 
    CAS 

    Google Scholar
     

  • Huang, S. et al. Single-layer graphene membranes by crack-free transfer for gas mixture separation. Nat. Commun. 9, 2632 (2018).

    Article 
    ADS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Dakhchoune, M. et al. Gas-sieving zeolitic membranes fabricated by condensation of precursor nanosheets. Nat. Mater. 20, 362–369 (2021).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zecchin, S., Schiavon, G. & Bombi, G. G. Interdiffusion coefficient of water in molten hydroxides. J. Electroanal. Chem. Interfacial Electrochem. 50, 261–267 (1974).

    Article 
    CAS 

    Google Scholar
     

  • Miles, M. H. Exploration of molten hydroxide electrochemistry for thermal battery applications. J. Appl. Electrochem. 33, 1011–1016 (2003).

    Article 
    CAS 

    Google Scholar
     



  • Source link

    Related posts

    The news of resumed shipments through the Hormuz Strait has boosted precious metals, with analysts optimistic about gold returning to $5,000.

    D.William

    Blackened Rings: The Hot New Take on Vintage Jewelry Trends

    D.William

    Chance the Rapper’s Coloring Book Earns 11 New RIAA Certifications

    D.William

    Leave a Comment