PI Global Investments
Precious Metals

A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II


  • Alstrum-Acevedo, J. H., Brennaman, M. K. & Meyer, T. J. Chemical approaches to artificial photosynthesis. 2. Inorg. Chem. 44, 6802–6827 (2005).

    Article 
    CAS 

    Google Scholar
     

  • Sun, L., Hammarström, L., Åkermark, B. & Styring, S. Towards artificial photosynthesis: ruthenium–manganese chemistry for energy production. Chem. Soc. Rev. 30, 36–49 (2001).

    Article 
    CAS 

    Google Scholar
     

  • Gust, D., Moore, T. A. & Moore, A. L. Solar fuels via artificial photosynthesis. Acc. Chem. Res. 42, 1890–1898 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Sala, X., Romero, I., Rodríguez, M., Escriche, L. & Llobet, A. Molecular catalysts that oxidize water to dioxygen. Angew. Chem. Int. Ed. 48, 2842–2852 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Umena, Y., Kawakami, K., Shen, J-R. & Kamiya, N. Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å. Nature 473, 55–60 (2011).

    Article 
    CAS 

    Google Scholar
     

  • Dismukes, G. C. et al. Development of bioinspired Mn4O4-cubane water oxidation catalysts: lessons from photosynthesis. Acc. Chem. Res. 42, 1935–1943 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Romain, S., Vigara, L. & Llobet, A. Oxygen–oxygen bond formation pathways promoted by ruthenium complexes. Acc. Chem. Res. 42, 1944–1953 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Dau, H. et al. The mechanism of water oxidation: from electrolysis via homogeneous to biological catalysis. ChemCatChem 2, 724–761 (2010).

    Article 
    CAS 

    Google Scholar
     

  • Meyer, T. J. Chemical approaches to artificial photosynthesis. Acc. Chem. Res. 22, 163–170 (1989).

    Article 
    CAS 

    Google Scholar
     

  • McDaniel, N. D., Coughlin, F. J., Tinker, L. L. & Bernhard, S. Cyclometalated iridium(III) aquo complexes: efficient and tunable catalysts for the homogeneous oxidation of water. J. Am. Chem. Soc. 130, 210–217 (2008).

    Article 
    CAS 

    Google Scholar
     

  • Hull, J. F. et al. Highly active and robust Cp* iridium complexes for catalytic water oxidation. J. Am. Chem. Soc. 131, 8730–8731 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Lalrempuia, R., McDaniel, N. D., Müller-Bunz, H., Bernhard, S. & Albrecht, M. Water oxidation catalyzed by strong carbene-type donor–ligand complexes of iridium. Angew. Chem. Int. Ed. 49, 9765–9768 (2010).

    Article 
    CAS 

    Google Scholar
     

  • Mullins, C. S. & Pecoraro, V. L. Reflections on small molecule manganese models that seek to mimic photosynthetic water oxidation chemistry. Coord. Chem. Rev. 252, 416–443 (2008).

    Article 
    CAS 

    Google Scholar
     

  • Wasylenko, D. J., Ganesamoorthy, C., Borau-Garcia, J. & Berlinguette, C. P. Electrochemical evidence for catalytic water oxidation mediated by a high-valent cobalt complex. Chem. Commun. 47, 4249–4251 (2011).

    Article 
    CAS 

    Google Scholar
     

  • Dogutan, D. K., McGuire, R. & Nocera, D. G. Electocatalytic water oxidation by cobalt(III) hangman β-octafluoro corroles. J. Am. Chem. Soc. 133, 9178–9180 (2011).

    Article 
    CAS 

    Google Scholar
     

  • Yin, Q. et al. A fast soluble carbon-free molecular water oxidation catalyst based on abundant metals. Science 328, 342–345 (2010).

    Article 
    CAS 

    Google Scholar
     

  • Ellis, W. C., McDaniel, N. D., Bernhard, S. & Collins, T. J. Fast water oxidation using iron. J. Am. Chem. Soc. 132, 10990–10991 (2010).

    Article 
    CAS 

    Google Scholar
     

  • Fillol, J. L. et al. Efficient water oxidation catalysts based on readily available iron coordination complexes. Nature Chem. 3, 807–813 (2011).

    Article 
    CAS 

    Google Scholar
     

  • Gersten, S. W., Samuels, G. J. & Meyer, T. J. Catalytic oxidation of water by an oxo-bridged ruthenium dimer. J. Am. Chem. Soc. 104, 4029–4030 (1982).

    Article 
    CAS 

    Google Scholar
     

  • Duan, L., Fischer, A., Xu, Y. & Sun, L. Isolated seven-coordinate Ru(IV) dimer complex with [HOHOH]− bridging ligand as an intermediate for catalytic water oxidation. J. Am. Chem. Soc. 131, 10397–10399 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Nyhlén, J., Duan, L., Åkermark, B., Sun, L. & Privalov, T. Evolution of O2 in a seven-coordinate RuIV dimer complex with a [HOHOH]−1 bridge: a computational study. Angew. Chem. Int. Ed. 49, 1773–1777 (2010).

    Article 

    Google Scholar
     

  • Xu, Y. et al. Chemical and light-driven oxidation of water catalyzed by an efficient dinuclear ruthenium complex. Angew. Chem. Int. Ed. 49, 8934–8937 (2010).

    Article 
    CAS 

    Google Scholar
     

  • Bozoglian, F. et al. The Ru-Hbpp water oxidation catalyst. J. Am. Chem. Soc. 131, 15176–15187 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Cooper, V. R. et al. Stacking interactions and the twist of DNA. J. Am. Chem. Soc. 130, 1304–1308 (2007).

    Article 

    Google Scholar
     

  • Sarkhel, S., Rich, A. & Egli, M. Water-nucleobase ‘stacking’: H–π and lone pair–π interactions in the atomic resolution crystal structure of an RNA pseudoknot. J. Am. Chem. Soc. 125, 8998–8999 (2003).

    Article 
    CAS 

    Google Scholar
     



  • Source link

    Related posts

    Why Is Wheaton Precious Metals (TSX:WPM) In Focus?

    D.William

    South African Export Stocks That Could Benefit If US Tariffs Are Softened

    D.William

    Why has India hiked custom duties on gold, silver and other precious metals?

    D.William

    Leave a Comment